Battery Articles | Amicell - Vencon https://www.vencon.com/category/battery-education/ UBA5 Tue, 02 Apr 2019 21:16:55 +0000 en-US hourly 1 https://wordpress.org/?v=6.8.1 Shipping Lithium Ion Batterieshttps://www.vencon.com/shipping-lithium-ion-batteries/ Thu, 13 Dec 2018 06:38:35 +0000 http://www.vencon.com/?p=1372UN3480: Lithium ion batteries must be shipped at 30% State of Charge (SOC) or less.

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Shipping & Storing Lithium Ion Batteries

UN3480: Lithium ion batteries must be shipped at 30% State of Charge (SOC) or less.

Lithium ion batteries should be stored at 20% to 50% State of Charge (SOC).

There are two methods to set a lithium ion battery to a specific SOC

1) Starting with a known SOC and adding or subtracting capacity from the battery.

2) Charging or discharging the battery until it reaches a specific voltage that represents the desired SOC.

Below we explain the UBA procedure to implement each of the above methods. The maximum SOC for shipping lithium ion batteries is 30% so we use a target value of 25% which allows a 5% margin and also is ideal for storing lithium batteries.

1) Starting with a known SOC:

There are two well defined SOC states: a fully charged battery is 100% and a fully discharged battery is 0%. The easiest way to put a battery at a 30% SOC is to start with it fully discharged and then charge it 30%.

This is how you would do it with the UBA5:


First do a full discharge on the battery by discharging the battery down to 2.75V per cell with a discharge action:


Then charge it back up to the desired SOC, 25% in this example:

After these two actions, the battery will be at 25% SOC.

This method works best if it’s performed immediately after a battery capacity test, as all that’s required is a 25% charge (approximately 20 minutes).

If you don’t need to measure the battery’s capacity then you can go directly to a specific SOC by using the voltage method explained below.

2) Charging or Discharging to a Specific Voltage

This method is more complicated then the previous method but it doesn’t require a full discharge. We present it to show some of the more advanced features of the UBA5. Don’t let the complexity scare you, as we include a battery analysis routine (BAR) using this method with our software.

We know that lithium ion batteries have a direct resting open circuit voltage (OCV) vs SOC relationship so in this method we’ll use that relationship. The OCV for a 25% SOC is 3.75V per cell. So we’ll charge the battery to 3.9V per cell (i.e. greater then our 25% target SOC) then discharge it to 3.65V per cell. Why 3.65V instead of 3.75? Because there’s a bit of “bounce back” where if you discharge a battery to a certain value, then remove the load, the battery’s voltage will rise back up. The amount of “bounce back” depends on the relative discharge current, the higher the discharge current, the higher the bounce back. The method we use is to discharge to 3.65V at 1C then repeat the discharge to 3.65V at decreasing currents until we reach 0.1C, then at that point we exit the routine.

ShipLIM2_1

To do this we start with a current of 1C (in the screen shot below, the variable load is set to 1.25C (1.0/0.8), and gets reduced to 1C on the first discharge).

ShipLIM2_2
We specify a Load current of 80% of the previous discharge and a Cut off voltage of 3.65V:

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Then repeat this ten times:

So basically we’re discharging at 1C to 3.65V per cell, then 0.8C to 3.65V, then 0.64C to 3.65V, …., and finally at 0.1C to 3.65V. All these parameters are adjustable so that the final SOC is reached as quickly as possible within the desired accuracy.

Setting the SOC with “One Click”

The above setup is designed by your engineering department, so that the operator only has to click one button to set the battery to a specific SOC. Here we’ve made two buttons for the operator, click the first button to measure battery capacity, or click the second button to put the battery into a 25% SOC. The flexibility and power of the UBA5 software is such that you can add as many buttons as you want, name them, and have them run any analysis that you’ve written. All these capabilities are in the software that’s included with your UBA5!

Showing Custom Buttons

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Standard vs Trickle Charging NiCd and NiMH Batterieshttps://www.vencon.com/charging-nicd-nimh-batteries/ Fri, 26 Dec 2014 16:03:28 +0000 http://www.vencon.com/?p=42Two methods of NiCd and NiMH charging -- standard and trickle.

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By Marc Venis B.A.Sc., M.A.Sc., P.Eng.
President Vencon Technologies Inc.

Standard Charging

In this article I discuss the two methods of NiCd and NiMH charging — standard and trickle. The “overnight” charger that comes with most rechargeable powered products charges at a rate of C/10 (the C rate is the hour capacity of the battery, i.e. a typical AA NiCd battery of 600mAh capacity has a C rate of 600mA, and a C/10 rate of 60mA). There is a very good reason why the manufacturer chose this rate. If the charger uses a higher rate, it would have to detect when the batteries are fully charged and shut off, or risk damaging them. This would make the charger more complex, and hence more expensive. Lower charge rates than C/10 unnecessarily extend the charging time, and in fact at very low rates (below C/50) the batteries never fully charge no matter how long you wait.

Thus the C/10 charging rate is a compromise between keeping the charger simple, yet charging the batteries in an acceptable amount of time. At the C/10 rate the battery will reach a full charge after approximately 14 to 16 hours. If the actual battery capacity was the same as its rated value, and its charging efficiency was 100% then only 10 hours would be necessary to fully charge a battery. But, actual capacity is usually greater than rated and charging efficiency is always less than 100%, thus 14 to 16 hours of C/10 charging ensures a fully charged battery. At this point any further charging only results in an increase in temperature and internal cell pressure. This does not damage the battery, although it accelerates their deterioration thus reduces their reliability.

Now that we know what the standard charger is, how do we use it? Most important, follow the manufacturer’s instructions. A typical manufacturer recommends a 15 hour charge to fully charge a discharged battery. If your battery is only partially discharged, your can prorate the charge time. For instance, a battery that is one third discharged will fully charge in only 5 hours. If you don’t know the condition of your battery, then you should charge it for the full 15 hours. What happens if you forget to disconnect the charger and end up charging for more than the required amount? If you overcharge by only a few hours, don’t worry. If you leave your charger connected for a couple of days, then you’re unduly stressing your batteries. If you’re the forgetful or worrying type, then you might want to use a timer. I like to use the standard 24 hour security timer, used to switch lights on and off when you’re away. It is sold almost anywhere, usually less than $10 on sale. To use a timer with removable ON/OFF pins for standard charging, first rotate the time dial until 12 midnight. Now insert an OFF pin at the 3pm position (15 hours) and remove any remaining pins (figure 1). Now plug your charger into the timer and the timer into a wall socket. Rotate the on/off switch on the timer until your charger turns on, and leave it alone. After 15 hours your charger will shut off and remain so. If you have a timer without removable pins set it up as above, but instead of inserting an OFF pin at 3pm, set an ON/OFF pin (or if separate pins, the ON and OFF pins together) at 2:30pm such that the timer will turn on at 2:30pm and off at 3pm (figure 2). It will operate similar to a single cycle timer, except on subsequent days the charger will turn on for one half hour each day (actually an advantage as we’ll see later).

Figure 1.

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Figure 2.

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Trickle Charging

I’m calling this section “Trickle Charging” because that’s the term we are all familiar with. This section is really about keeping your batteries fully charged. Trickle charging is one way to do that, charge replacement the other. To avoid confusion, I’ll use the term “trickle charging” to refer to any method of keeping your batteries fully charged.

Now that we know how to fully charge our batteries, when do we trickle charge? If you usually charge your batteries the day before you intend to use them, you don’t need to trickle charge. If, on the other hand, you’re like me and want to have all your batteries charged and ready to go, you need a trickle charging system.

NiCds and NiMH cells, like all batteries, self-discharge. NiCds and NiMH actually have a relatively high self-discharge rate of about 1% per day at room temperature (i.e. a 600mAh cell loses about 6mAh each day). The purpose of trickle charging is to replace the charge that is continually draining off.

Trickle charging is similar to standard charging (i.e. it uses a continuous charging current), only less current is used, between C/50 and C/20 (i.e. between 12mA and 30mA for a 600mAh cell). This rate is high enough to maintain a charged battery fully charged, yet low enough to permit continuous charging while keeping cell temperature and internal cell pressure at a safe level.

Since I doubt a trickle charger came with your battery, we will need to be a bit more inventive if we want to trickle charge our batteries (or you can go out and buy a commercial trickle charger). There are three basic methods used in our hobby to trickle charge.

Method 1. Continuous Current.

The simplest method of trickle charging (at least for a manufacturer) is to just reduce the charging current to about C/40. If the charger already charges at the standard C/10 rate, then all the manufacturer need do is add a resistor (and possibly a switch for trickle/standard mode and a charge indicator LED). This is the method used by most trickle chargers.

Method 2. Pulsed Current.

If we switch a C/10 standard charger on and off such that it is on for only 10% of the time, we would be continuously replacing any lost charge. We could do this by switching a C/10 charger on for one second off for nine seconds. This is similar to the method used by the Ultimate Battery Analyzer. This is more complicated for the manufacturer than the continuous current method, but easier for the user. If we switch the AC side of our standard chargers, we can simultaneously trickle charge all our batteries. Unfortunately the 24 hour security timer can’t switch on and off fast enough for this method, but it can do something else, as shown below.

Method 3. Daily Charge Replacement.

This method allows the battery to self-discharge during the day then it replaces the lost charge once per day. It is a simple and inexpensive method. Set the timer to turn on for at least one half hour each day. Plug your chargers into the timer (a power bar comes in handy here), and the timer into the AC socket. Everyday your batteries will get a top-up charge and will be ready for use.

What would happen if you accidentally connect a fully or partially discharged battery to your trickle charger? Method 1 has the advantage that it will charge the battery in about 3 days (although this isn’t recommended because the battery might not reach its maximum capacity, you should always charge at the C/10 rate). Methods 2 and 3 with their slower charging could take over a month. Increasing the duty cycle ‘on’ time of methods 2 and 3 will reduce the charging time, but at the expense of slightly greater heating. You can increase method 2’s duty cycle up to 25% (1 second on, 3 seconds off) with little adverse effects. At 25% duty cycle, full charge will take four times as long as at the C/10 rate (about 3 days). Increasing method 3’s duty cycle to 25% will warm the pack for 6 hours every day.

An important consideration of which method you choose is verifying that the packs are on trickle charge. Method 2 has the advantage that you can see the flashing charge lights and know that the system is working. Method 1 does not draw enough current from the charger to light its LEDs, thus unless you have installed additional charge LEDs it is impossible to tell if the battery is actually charging. Since method 3 only turns on the charger for one half hour each day it is difficult to verify its operation. Method 1 also has the disadvantage in that being a continuous charging system, it promotes cadmium migration. Cadmium migration is something we want to avoid, and pulse charging (methods 2 and 3) reduce the chances of it happening.

Which trickle charging system is best for you? Unless you have a convenient method of pulse charging, I recommend method 3 for its simplicity and economy (and that’s the method I use).

A Personal Charging System

Now let’s combine a standard and trickle charger to assemble your own charging system. You can use your security timer to charge your batteries, then automatically trickle charge them. Remember where a timer without removable pins was used to charge up you batteries. During the first day the batteries charge for 15 hours. On subsequent days the batteries charge an additional one half hour. This will keep them fully charged and ready for use. You can do the same using a single cycle timer. Just insert the ON pin one half hour before the OFF pin. You can now leave and forget about it.

If you know that you’re not going to be using your battery for more than a couple of months, take your batteries off your trickle charger and just remember to fully charge them before use. Also, even though your batteries are on trickle charge, you still need to do a full discharge test every month or so to ensure their condition. One final note of caution. The first couple of times using a new trickle charger system insure that the batteries are really fully charged before you use them. Ideally, you would measure their capacity at least a day before using them by a discharge test and then fully charge them.

I hope that this information instills in you a bit more knowledge about charging your batteries.

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Preventing Battery Failureshttps://www.vencon.com/testing-batteries/ Fri, 26 Dec 2014 15:55:45 +0000 http://www.vencon.com/?p=36The key to preventing battery failures is to minimize any misuse and to track their capacity and other key characteristics.

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By Marc Venis B.A.Sc., M.A.Sc., P.Eng., President Vencon Technologies Inc.

The key to preventing battery failures is to minimize any misuse and to track their capacity and other key characteristics. A battery monitoring program will identify a rapidly deteriorating battery before it actually fails.

The first part of a battery monitoring program is to regularly measure their capacity. Capacity is the amount of charge available from a battery, measured in ampere-hours (Ah) for large cells, milliampere-hours (mAh) for smaller cells. A typical AA size battery has a rated capacity of 600mAh, thus it can supply 600mA for at least one hour or 100mA for at least six hours. Manufacturers conservatively rate battery capacity so that, in general, the measured capacity (which we discuss below) should be greater than the rated amount.

The basic concept used by all battery analyzers to check capacity is to connect the battery to a known accurate constant current load and monitor the voltage as the battery discharges (figure 1).

art1fig1
When the battery voltage reaches a predetermined value (the cut off voltage), the load is disconnected and the elapsed time recorded. The battery capacity is simply the load current times the elapsed time in hours. Normally, you would start this test with a fully charged battery. You can check a battery’s capacity using this method with only a resistor as load, a voltmeter, and a stop watch. Alternately, you can use a commercial battery analyzer (such as the Ultimate Battery Analyzer our company makes).

There are many commercial analyzers available, ranging in price from $200 to $2000 or more. The best one for you depends on features you need and your budget. The less expensive models are limited in their accuracy and customization. The more expensive models allow you to test more types of batteries and many batteries at once.

Operation of all the commercial units is similar: first, connect a power source to the analyzer, an AC plug, a wall adapter (power supply) or a 12V battery. Specify the battery being tested (i.e. a Motorola 550 cell phone) or specify the test conditions (i.e. number of cells, charging and discharging current, depth of discharge). Then connect the analyzer to the battery that is being tested. Press the start button and leave the analyzer and battery alone for a few hours. The analyzer discharges the battery, measures the discharge time then recharges the batteries. After the discharge is completed the analyzer shows your battery’s capacity.

The measured capacity depends on the following factors: battery temperature, discharge current, cut-off voltage, and the battery’s prior history. Below room temperature (20 degree C) battery capacity is reduced. You should make all your measurements between 18 degree C and 25 degree C.

What discharge current should you use? Most manufacturers (Sanyo and Panasonic for example), measure capacity at a discharge rate of C/5, which is called the five hour discharge rate. For example, a typical AA cell of 600mAh capacity would have a ‘C’ of 600mA and a C/5 of 120mA. Others measure capacity at a discharge rate of C. Like all batteries, the higher the discharge current, the less the available capacity. For example, the available capacity with a discharge at C/5 is about 10% more than that with a discharge at the C rate. Another possible discharge current would be the actual current drain of the battery while being used. I recommend that you discharge at between C and C/2.

At what point do you stop the discharge? If you choose too high of a figure, you won’t fully discharge the cells. If you choose too low a figure, you might force one of the cells into reverse polarity (not a good situation). Usually a cut-off voltage of 1.05V/cell is used when discharging at the C/5 rate and 0.9V/cell when discharging at the C rate. Or you can use the formula:

Vcutoffper_pack=1.2V * (Ncells-1)

Which gives a cut off of 0.9V per cell for a four cell battery pack, and 1.05V for an eight cell battery pack.

What does prior history have to do with a battery’s capacity? A battery that was quick charged or charged at above room temperature will not generally be fully charged. Nor will a battery that was charged after being stored for a few months. For these reasons I recommend that before a capacity test, the battery be charged at C/10 for 18 hours to 24 hours at room temperature. If the battery had been stored for a few months, is new, or hasn’t been tested in a few months, a second and possibly a third capacity test is recommended.

One additional measurement you can make during a discharge experiment is the “midpoint voltage.” This is the voltage midway through a discharge test. If you have our Ultimate Battery Analyzer, you can simply read it off the graph (midpoint voltage figure 2), otherwise you will have to use an accurate voltmeter to measure the voltage yourself during the battery discharge. Record this voltage.

art1fig2

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